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The method was developed by Willard Libby in the late 1940s and soon became a standard tool for archaeologists.
Libby received the Nobel Prize in Chemistry for his work in 1960.
The older a sample is, the less (the period of time after which half of a given sample will have decayed) is about 5,730 years, the oldest dates that can be reliably measured by this process date to around 50,000 years ago, although special preparation methods occasionally permit accurate analysis of older samples.
The idea behind radiocarbon dating is straightforward, but years of work were required to develop the technique to the point where accurate dates could be obtained.
Other corrections must be made to account for the proportion of throughout the biosphere (reservoir effects).